improving the fast-charging performances of LIBs, in which the enhancements of anode materials are undisputedly important. [4] Graphite, the most commonly used anode material in LIBs, mainly faces the following problems: 1) The small interlayer distance of graphite (0.33 nm) is far from sufficient to perform rapid Li + transport; 2) During the fast charging, high current densities result in Li dendrite growth on graphite anode and thereby raising serious safety concerns; [5,6] 3) With the specific capacity of graphite anode approaching its ceiling (372 mAh g −1 ), further increase in capacity is expected to encounter huge challenges and thus limited energy density. Various anode materials, such as metal oxides (SnO 2 ), [7] metal sulfides (WS 2 , SnS 2 , Sb 2 S 3 ), [8] SiO x (0 < x < 2), [9] metals (Sn, Sb, Ge, Li), etc., [10,11] have been extensively explored as anode materials for fastcharging LIBs.Among them, tungsten disulfide (WS 2 ) with tunable interlayer distance, high theoretical capacity (432 mAh g −1 ), and large density (7.6 g cm −3 , about three-times larger than graphite) has drawn significant attention as fast-charging anode material for LIBs. [12][13][14] However, several critical challenges, such as sluggish ion diffusion kinetics, poor intrinsic electrical conductivity, and large volume fluctuations upon cycling, should be addressed for the successful utilization of WS 2 in fast-charging LIBs. Defect engineering in terms of heteroatom doping with the strong capabilities of regulating the electronic structure and increasing ion storage sites shows huge advantages to offer the fast-charging capability. [15,16] Besides, the fabrication of nano structured WS 2 and conducted coatings is also a feasible strategy, [17] which shortens ion and electron diffusion path and increases electrical conductivity. However, the unimproved electron and ion transport inside WS 2 brings limited improvement of fast-charging capability. Constructing the few-layer WS 2 /carbon layer-by-layer stacked structure has been confirmed as an available strategy towards the above issues, [18] which increases the contact area between WS 2 and carbon, thus accelerating ionic and electronic transport. Nevertheless, maximizing the molecular layer contact area of WS 2 and C by constructing a stacked structure of single-layer WS 2 and C to further improve ionic and electronic transport is still a huge challenge and has not been realized so far.