In this study, bearing bushes made of polyetheretherketone (PEEK), 30 wt % carbon fibre reinforced PEEK, 30 wt % glass fibre reinforced PEEK, each 10 wt % of PTFE, graphite and carbon fibre modified PEEK were investigated on a purpose built pin joint test rig. The unlubricated friction and wear behaviour was assessed in sliding contact with a 300M shaft, subjected to a nominal pressure of 93 MPa, articulating sliding speed of 45 °/s. The worn surface and the subsurface layer were studied using optical profilometry and scanning electron microscopy (SEM). Due to thermal sensitivity of PEEK composites, friction energy and temperature rise were analysed for determining the friction and wear mechanism. The bush made of PTFE, graphite and carbon fibre (each 10 wt %) modified PEEK presented the best performance for friction coefficient, wear loss, friction energy and temperature rise. Current work demonstrated that reinforcement modified PEEK composite possesses desirable properties to perform as a load bearing bush in certain tribological applications.