“…The coatings, which are fabricated by physical vapor deposition (PVD) technology, such as chromium nitride (CrN), titanium nitride (TiN), zirconium nitride (ZrN), vanadium nitride (VN), diamond-like carbon (DLC), graphitelike carbon (GLC), and various composites based on the above-mentioned compounds (CrAlN, CrSiN, CrCN, CrAlSiN, TiAlN, TiSiN, TiCN, TiAlSiN, CrTiAlN, ZrCN, VAlN, Ti-DLC, Si-DLC, WC–DLC, Cr-GLC, etc.) with good properties like high wear resistance, corrosion protection, and low friction coefficient under variety of conditions, have become more and more popular in the field of material protection, such as drills, gears, bearings, molds, medical implants, seals, and instruments. − Nowadays, the thickness of the coatings is an important parameter having drawn considerable interest in these applications. − For the traditional thin coatings, low load-bearing capacity, low lifetime, and damages that quickly reach down to the substrate have restricted the development of PVD coatings in more and more severe mechanical application conditions, such as high working temperatures, high humidity, high salt spray, and high work load carrying. − However, most PVD coatings generally are limited by small thickness because of the mismatch in the chemical bonding between the coating and substrate, high interfacial free energy, ion-peening mechanism, and the disbanding problem. − Thus, the design and development of thicker PVD protective coatings are most desired and important in fundamental research and industrial applications. In recent years, many researchers have fabricated the wide variety of PVD coatings with high thickness based on the two design concepts of doping C, Si, W, Cr, Al, and other elements and fabricating multilayer coatings. ,, For example, the thick silicon multilayer (20 μm) with alternate compressive/tensile stress layer pairs was designed and deposited by Yang et al Lin et al also have deposited the thick-layered nanocomposite Ti–Si–C–N coatings .…”