With the use of the high-performance precision mould, the requirements on the high speed, high reliable mould parts become more and more stringent. In order to further improve the surface wear resistance of moulds, Fe-Mn-Cr alloy coatings was prepared by a duplex treatment consisting of laser cladding followed by plasma nitriding. A dense structure coating with no cracks, pores or other defects were obtained after the duplex treatment, presenting a good metallurgical bonding to the substrate. After the duplex treatment, a nitride-layer of ξ-Fe 2 N+Cr 2 N and α-Fe with nitrogen were formed on the coating surface. The in uence of the duplex treatment on the hardness and wear resistance of the cladding layer were investigated. The hardness of the coating signi cantly increased, with an average microhardness of 1788 HV, which ensured the wear resistance of the coating. Comparing with laser cladded coating, the samples with duplex treated coating dropped about 41% in wear rate, and performed a better wear resistance. The main wear mechanism of the samples with duplex treated coating was abrasive wear.