Tribovoltaic Performance of TiO₂ Thin Films: Crystallinity, Contact Metal, and Thermoelectric Effects

Abstract

Tribovoltaic devices are attracting increasing attention as motion-based energy harvesters due to the high local current densities that can be generated. However, while these tribovoltaic devices are being developed, debate remains surrounding their fundamental mechanism. Here, we fabricate thin films from one of the world’s most common oxides, TiO2, and compare the tribovoltaic performance under contact with metals of varying work functions, contact areas, and applied pressure. The resultant current density shows little correlation with the work function of the contact metal and a strong correlation with the contact area. Considering other effects at the metal–semiconductor interface, the thermoelectric coefficients of different metals were calculated, which showed a clear correlation with the tribovoltaic current density. On the microscale, molybdenum showed the highest current density of 192 mA cm–2. This work shows the need to consider a variety of mechanisms to understand the tribovoltaic effect and design future exemplar tribovoltaic devices.

Tribovoltaic Effect: Origin, Interface, Characteristic, Mechanism & Application

“…j) Normalized Seebeck effect voltage. (Adapted from Šutka* et al [70] Copyright 2023 American Chemical Society).…”

“…The results show that there is a significant correlation between the thermoelectric coefficients and the current density of TVNG, among which the current density of molybdenum is the highest, reaching 192 mA cm −2 (Figure 17j ), which provides a new idea for understanding the coupling mechanism of tribo‐thermoelectric effect. [ 70 ]…”

“…The results show that there is a significant correlation between the thermoelectric coefficients and the current density of TVNG, among which the current density of molybdenum is the highest, reaching 192 mA cm −2 (Figure 17j), which provides a new idea for understanding the coupling mechanism of tribo-thermoelectric effect. [70] By studying the multi-physical field coupling effect of friction and semiconductor, it can further promote the multi-energy harvesting and sensing based on semiconductor interfaces.…”