Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect
Xiaoxue Ma,
Xin Li,
Xueke Han
et al.
Abstract:Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
The amphiphilic {[Cd3(L)2(phen)2(H2O)6]·2H2O·2DMF}n (1) (H3L = 1, 3, 5-benzenetricarboxylic acid, phen = phenanthroline) and hydrophilic [Zn3(L)2(H2O)12]n (2) were obtained by hydrothermal reactions. Compound 1 is less hydrophilic due to its...
The amphiphilic {[Cd3(L)2(phen)2(H2O)6]·2H2O·2DMF}n (1) (H3L = 1, 3, 5-benzenetricarboxylic acid, phen = phenanthroline) and hydrophilic [Zn3(L)2(H2O)12]n (2) were obtained by hydrothermal reactions. Compound 1 is less hydrophilic due to its...
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