2007
DOI: 10.3998/ark.5550190.0008.610
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Trifluoroacetic anhydride-sodium iodide reagent. Nature and applications

Abstract: Trifluoroacetic anhydride -sodium iodide mixture (TFAA-NaI; TFAA-I) reacts with several compounds bearing semipolar X-O bond, usually in the mode of deoxygenation, with liberation of iodine. The results of systematic investigations of the TFAA-I-reaction with various types of S-oxo and N-oxo compounds were discussed. The majority of these reactions are characterized by quantitative course, with respect to both X-O substrate transformation as well as to the amounts of liberated iodine. On this basis, a variety … Show more

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