Trimethylstannyl (diphenylphosphino)acetate: a source of (diphenylphosphino)acetate ligand in the synthesis of coordination compounds

Reactions of CO2 and CS2 with [RuH(η2-CH2PMe2)(PMe3)3]

“…The ruthenium–phosphine bond distances are unexceptional. The ruthenium–oxygen bond distance, 2.201(3) Å, is slightly longer than typically observed for ruthenium acetate bonds, but is entirely consistent with the only other structurally characterized ruthenium phosphinoacetate complex, [Ru( p -cymene)Cl(OC(O)CH 2 PPh 2 -κ 2 - O , P )]·SnMe 3 Cl (2.100(2) Å) …”

Bonding and Organic and Inorganic Reactivity of Metal-Coordinated Phosphinoenolates and Related Functional Phosphine-Derived Anions

“…When a phosphinocarboxylate ligand chelates a metal center, the CO oxygen is expected to be a better donor than the MO oxygen. Accordingly, the carboxylate function of the Rh(III) complex obtained by reaction of Ph 2 PCH 2 CO 2 Na with [Cp*Rh(μ-Cl)Cl] 2 , acts as a Lewis base toward Sn(IV) reagents, as in 106 . A similar situation was observed with an arene Ru(III) complex …”

“…As mentioned above, protonation of 31 afforded cationic clusters containing a bridging, ketophosphine ligand L 2 . , However, hydrolysis of the ester function of 23a,b led to the phosphinocarboxylate complexes 34a,b (eq 9), which could be obtained directly by reaction of with Ph 2 PCH 2 CO 2 Na . Likewise, reaction of 2 equiv of this salt with [PdCl 2 (NCPh) 2 ] afforded which was recently characterized by X-ray diffraction …”

Preparation and structural characterization of simple and donor-substituted triorganostannyl 1′-(diphenylphosphino)-1-ferrocenecarboxylates and their P-chalcogenide derivatives

“…Stimulated by the seminal work of Ng and Zuckerman dealing with triorganostannyl esters of phosphorus-substituted acetic acids, Ph 2 P(E)CH 2 CO 2 SnR 3 (E/R = O/alkyls and Ph, S/Ph) and (Ph 2 P(O)CH 2 CO 2 ) 2 SnR 2 (R = Me, Ph) [3], their related phosphonium salts [Ph 3 P(CH 2 ) 2 CO 2 SnR 3 ]X (R = Me and Ph; X = various anions) [4], and also by the work of Cross et al reporting the synthesis of [CH 3 CH(P(O)Ph 2 )CO 2 ] 4Àn SnR n (R = Me, Ph; n = 2, 3) [5,6], we have recently prepared trimethylstannyl (diphenylphosphino)acetate and studied this compound in reactions with transition metal precursors leading to phosphinocarboxylate complexes [7]. Later, we expanded our study towards the synthesis and structural characterization of the related compounds possessing donor-functionalized (L NC )R 2 Sn groups (R = Me and Ph; L NC = 2-[(dimethylamino)-methyl]phenyl) [8].…”