Triple‐oxygen isotopes of stony micrometeorites by secondary ion mass spectrometry (SIMS): Olivine, basaltic glass and iron oxide matrix effects for sensitive high‐mass resolution ion microprobe‐stable isotope (SHRIMP‐SI)

Abstract

RationaleMicrometeorites are extraterrestrial particles smaller than ~2 mm in diameter, most of which melted during atmospheric entry and crystallised or quenched to form ‘cosmic spherules’. Their parentage among meteorite groups can be inferred from triple‐oxygen isotope compositions, for example, by secondary ion mass spectrometry (SIMS). This method uses sample efficiently, preserving spherules for other investigations. While SIMS precisions are improving steadily, application requires assumptions about instrumental mass fractionation, which is controlled by sample chemistry and mineralogy (matrix effects).MethodsWe have developed a generic SIMS method using sensitive high‐mass resolution ion micro probe‐stable isotope (SHRIMP‐SI) that can be applied to finely crystalline igneous textures as in cosmic spherules. We correct for oxygen isotope matrix effects using the bulk chemistry of samples obtained by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) and model bulk chemical compositions as three‐component mixtures of olivine, basaltic glass and Fe‐oxide (magnetite), finding a unique matrix correction for each target.ResultsOur first results for cosmic spherules from East Antarctica compare favourably with established micrometeorite groups defined by precise and accurate but consumptive bulk oxygen isotope methods. The Fe‐oxide content of each spherule is the main control on magnitude of oxygen isotope ratio bias, with effects on δ18O up to ~6‰. Our main peak in compositions closely coincides with so‐called ‘Group 1’ objects identified by consumptive methods.ConclusionsThe magnitude of SIMS matrix effects we find is similar to the previous intraspherule variations, which are now the limiting factor in understanding their compositions. The matrix effect for each spherule should be assessed quantitatively and individually, especially addressing Fe‐oxide content. We expect micrometeorite triple‐oxygen isotope compositions obtained by SIMS to converge on the main clusters (Groups 1 to 4) after correction firstly for magnetite content and secondarily for other phases (e.g., basaltic glass) in each target.