Tris(1,10-phenanthroline)nickel(II) di-μ-iodo-bis(diiodomercurate)N,N-dimethylformamide solvate monohydrate

Abstract

Key indicatorsSingle-crystal X-ray study T = 292 K Mean (C-C) = 0.009 Å R factor = 0.041 wR factor = 0.095 Data-to-parameter ratio = 20.7For details of how these key indicators were automatically derived from the article, see

Hydrogen-bonding and π–π stacking interactions in tris(1,10-phenanthroline-κ2N,N′)nickel(II) bis{[1-tert-butylimidazole-2(3H)-thione-κS]trichloridonickelate(II)} acetonitrile disolvate

“…For general background, see: Fatimi et al (1994); Iradyan et al (1987); Suescun et al (1999); Yu et al (2003); Fang & Dai (2006); Chen et al, (2007); Senda et al (2006). For synthesis details, see: Kister et al (1979).…”

“…(Fatimi et al, 1994;Iradyan et al, 1987). The literature revealed the presence of various nickel(II) complexes with phenanthroline (Suescun et al, 1999;Yu et al (2003); Fang & Dai, 2006;Chen et al, 2007) but none with N-tert-butyl-2thioimidazole, except the one reported recently (Senda et al, 2006). The present work reports the first structure of a nickel(II) complex with N-tert-butyl-2-thioimidazole and 1,10 phenanthroline, containing a tetrahedral anion, [Ni(tm) The Ni-Cl bond distances are in the range of 2.251 (15) to 2.275 (15) Å.…”