2013
DOI: 10.1107/s1600536813027591
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Tris[4-bromo-2-(methyliminomethyl)phenolato-κ2N,O]cobalt(III)

Abstract: In the title compound, [Co(C8H7BrNO)3], the CoIII ion is coordinated in a slightly distorted octa­hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl­imino­meth­yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol­ecules are linked by pairs of weak C—H⋯Br hydrogen bonds, forming inversion dimers.

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“…For material and biological applications, see: Church & Halvorson (1959); Olsson et al (2005); Burschka et al 2013; Erkkila et al (1999); Metcalfe & Thomas (2003); Generex & Barton (2010). For related structures, see: Gupta et al (2012b); Huang et al (2013).…”
Section: Related Literaturementioning
confidence: 99%
“…For material and biological applications, see: Church & Halvorson (1959); Olsson et al (2005); Burschka et al 2013; Erkkila et al (1999); Metcalfe & Thomas (2003); Generex & Barton (2010). For related structures, see: Gupta et al (2012b); Huang et al (2013).…”
Section: Related Literaturementioning
confidence: 99%