Tris(tetraethylammonium) tris(μ-4-pyridinemethanolato)bis[tricarbonyltungsten(0)] acetonitrile trisolvate

Abstract

Key indicatorsSingle-crystal X-ray study T = 110 K Mean '(C±C) = 0.003 A Ê R factor = 0.018 wR factor = 0.042 Data-to-parameter ratio = 26.3For details of how these key indicators were automatically derived from the article, see

Tris(tetraethylammonium) μ-3-hydroxypropanolato-di-μ-methoxo-bis[tricarbonyltungsten(0)]

“…Previously, we have presented the results of ligand exchange of the trianion of (Et 4 N) 3 [W 2 (OMe) 3 (CO) 6 ], (II), with aryl alcohols (Klausmeyer et al, 2003). Subsequently, we reported the complete exchange reaction with an alcohol containing an sp 3 carbon (Klausmeyer & Adrian, 2004). In each of the previous examples, there was always complete exchange of all of the methoxy groups, regardless of how much of the new alcohol was added.…”