1993
DOI: 10.1016/s0277-5387(00)87084-9
|View full text |Cite
|
Sign up to set email alerts
|

Trispyrazolylborate degradation and the crystal structure of [Mo(NO)(CO)2{HB(OPri)(3-Pri-5-MeC3HN2)2}]

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4
1

Citation Types

0
12
0

Year Published

1995
1995
2019
2019

Publication Types

Select...
7
1

Relationship

0
8

Authors

Journals

citations
Cited by 17 publications
(12 citation statements)
references
References 18 publications
0
12
0
Order By: Relevance
“…However, circumstantial evidence does shed some light on possible pathways. First, it should be noted that there is limited precedent for alcoholysis of poly-(pyrazolyl)borates to provide alkoxy(pyrazolyl)borate complexes, 26,27 or indeed boron-free complexes. 28 Thus on (only) one occasion 26 27 Although the yields obtained were at best modest (R=Me, 20%; R=Et, 5%), the reactions were found to be reproducible.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…However, circumstantial evidence does shed some light on possible pathways. First, it should be noted that there is limited precedent for alcoholysis of poly-(pyrazolyl)borates to provide alkoxy(pyrazolyl)borate complexes, 26,27 or indeed boron-free complexes. 28 Thus on (only) one occasion 26 27 Although the yields obtained were at best modest (R=Me, 20%; R=Et, 5%), the reactions were found to be reproducible.…”
Section: Resultsmentioning
confidence: 99%
“…First, it should be noted that there is limited precedent for alcoholysis of poly-(pyrazolyl)borates to provide alkoxy(pyrazolyl)borate complexes, 26,27 or indeed boron-free complexes. 28 Thus on (only) one occasion 26 27 Although the yields obtained were at best modest (R=Me, 20%; R=Et, 5%), the reactions were found to be reproducible. Furthermore, the more sterically demanding K[H 2 B(pzMe 2 ) 2 ] proligand afforded the tetrahydrido derivatives [ReH 4 {κ 3 O,N,N 0 -HB(OR)(pzMe 2 ) 2 }-(PPh 3 )] in synthetically useful quantities (R = Me, 25%; R=Et, 60%).…”
Section: Resultsmentioning
confidence: 99%
“…Similar reactivity of tris-and bis-pyrazolylborates with alcohols has been observed previously. [37][38][39]…”
Section: Synthesismentioning
confidence: 99%
“…All these complexes were tetrahedral. The only octahedral complex reported was the structurally characterized [( i PrO)Bp*]Mo(CO) 2 NO, but the mechanism of its formation has remained obscure …”
Section: Resultsmentioning
confidence: 99%
“…The only octahedral complex reported was the structurally characterized [( i PrO)Bp*]Mo(CO) 2 NO, but the mechanism of its formation has remained obscure. 19 The structure of Tl[Tp (2,4(OMe) 2 Ph) ] (Figure 2) shows the ligand coordinating to Tl(I) in symmetrical fashion through the three pyrazolyl nitrogens. There is no additional coordination through the o-methoxy groups.…”
Section: Resultsmentioning
confidence: 99%