In recent years the Tsallis statistics is gaining popularity in describing charged particle production and their properties, in particular pT spectra and the multiplicities in high energy particle collisions. Motivated by its success, an analysis of the LHC data of proton-proton collisions at energies ranging from 0.9 TeV to 7 TeV in different rapidity windows for charged particle multiplicities has been done. A comparative analysis is performed in terms of the Tsallis distribution, the Gamma distribution and the shifted-Gamma distribution. An interesting observation on the inapplicability of these distributions at √ s=7 TeV in the lower rapidity windows is intriguing. The non-extensive nature of the Tsallis statistics is studied by determining the entropic index and its energy dependence. The analysis is extrapolated to predict the multiplicity distribution at √ s=14 TeV for one rapidity window, |y| < 1.5 with the Tsallis function.