Graphene,
as an optically transparent material, typically defies
any attempt for mid-infrared (mid-IR) absorption, which limits its
applications in mid-IR biosensing. Although remarkable evidence for
mid-IR nanopatterned graphene plasmons has been reported via the induction
of free charge carriers, no study so far has investigated plasmonic
excitation in nanopatterned graphene without employing induced voltage,
high chemical doping, or metallic reflectors. In this work, we show
that localized plasmon resonance (LSPR) can be probed in metal-free,
naturally doped, nanomembrane graphene (NMG) without induced voltage
or using metallic layers. We rely on facile, lithography-free, fabrication
methodology to pattern nanoscale holes in a single sheet of graphene
using Au nanoislands with hole dimensions as small as 10 nm. We image
the LSPR at the graphene membrane edges via scanning near-field optical
microscopy. Our experimental findings are confirmed by theoretical
electromagnetic field mapping at the graphene membrane edges leading
to noticeable absorption. We demonstrate the dependence of this absorption
wavelength on the hole diameter and interhole distance; hence, we
present a new avenue to fundamentally boost light harvesting with
naturally doped NMG which is pivotal for mid-IR sensors. We show that
our designed NMG can be used as a mid-IR biosensor with theoretically
calculated sensitivity of 825 nm/RIU.