2019
DOI: 10.1038/s41563-019-0532-z
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Tunable quadruple-well ferroelectric van der Waals crystals

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Cited by 190 publications
(218 citation statements)
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“…The sulfur 6 , 7 and selenium 8 – 10 compounds have similar structure of individual layers and a concomitant ferrielectric (FE) ordering, with Cu + and In 3+ ions counter-displaced within individual layers, against the backbone of P 2 Q 4- 6 anions. The spontaneous polarization of the sulfide can range from ~5 μC/cm 2 to ~12 μC/cm2 11 vs ~2.5 μC/cm 2 12 in the selenide, in part due to larger off-centric Cu displacement in the sulfide. Despite the structural similarity, the reported properties of their phase transitions are quite different 10 .…”
Section: Introductionmentioning
confidence: 99%
“…The sulfur 6 , 7 and selenium 8 – 10 compounds have similar structure of individual layers and a concomitant ferrielectric (FE) ordering, with Cu + and In 3+ ions counter-displaced within individual layers, against the backbone of P 2 Q 4- 6 anions. The spontaneous polarization of the sulfide can range from ~5 μC/cm 2 to ~12 μC/cm2 11 vs ~2.5 μC/cm 2 12 in the selenide, in part due to larger off-centric Cu displacement in the sulfide. Despite the structural similarity, the reported properties of their phase transitions are quite different 10 .…”
Section: Introductionmentioning
confidence: 99%
“…[26,27] Recently, density functional theory (DFT) demonstrated the presence of two iso-symmetric polar phases. [28] When the Cu ions reside within the layers, the predicted polarization is ≈5 μC cm −2 (termed the low polarization or LP phase) whereas if Cu occupies sites within the vdW gaps, the spontaneous polarization is predicted to double to ≈11 μC cm −2 (termed the high polarization or HP phase). Both phases are aligned either parallel (+) or antiparallel (−) to z, resulting in a quadruple-well energy potential as a function of Cu z displacement instead of the usual double-well potential.…”
Section: Introductionmentioning
confidence: 99%
“…Moreover, the material also exhibits giant negative electrostrictive coefficients, [24,29] which is a direct consequence of the highly anharmonic potential well. [28] In addition, CIPS has a high Cu-ion conductivity that extends into the temperature range of the ferroelectric phase. [30][31][32] It has been shown that in-plane ionic currents can be used to manipulate ferroelectric polarization.…”
Section: Introductionmentioning
confidence: 99%
“…Recently CuInP 2 S 6 (CIPS), a typical room-temperature van der Waals (vdW) layered ferroelectric crystal 19,20,21 , has attracted intensive attention due to its unexpected features including giant negative piezoelectricity 22 , tunable quadruple-well ferroelectric nature 23 , negative capacitance characteristic 24 and the interplay between ferroelectricity and ionic conductivity 25,26,27 . These unique characteristics not only bring new insights into the fundamental research 28,29 , but also provide new opportunities for diverse applications of layered ferroelectrics 30,31 .…”
Section: Introductionmentioning
confidence: 99%