By operating a one-electron quantum dot (fabricated between a multielectron dot and a oneelectron reference dot) as a spectroscopic probe, we study the spin properties of a gate-controlled multielectron GaAs quantum dot at the transition between odd and even occupation number. We observe that the multielectron groundstate transitions from spin-1/2-like to singlet-like to tripletlike as we increase the detuning towards the next higher charge state. The sign reversal in the inferred exchange energy persists at zero magnetic field, and the exchange strength is tunable by gate voltages and in-plane magnetic fields. Complementing spin leakage spectroscopy data, the inspection of coherent multielectron spin exchange oscillations provides further evidence for the sign reversal and, inferentially, for the importance of non-trivial multielectron spin exchange correlations. Semiconducting quantum dots with individual unpaired electronic spins offer a compact platform for quantum computation [1,2]. They provide submicron-scale two-level systems that can be operated as qubits [3][4][5][6][7][8] and coupled to each other via direct exchange or direct capacitive interaction. In these approaches, the essential role of nearest-neighbor interactions in larger and larger arrays of one-electron quantum dots [9-13] poses technological challenges to upscaling, due to the density of electrodes that define and control these quantum circuits. This issue has stimulated efforts to study long-range coupling of spin qubits either by electrical dipole-dipole interaction [12][13][14] or via superconducting microwave cavities [15][16][17]. However, these approaches involve the charge degree of freedom, which makes the qubit susceptible to electrical noise [18][19][20][21]. Recent work [22,23] indicates that the effective noise needs to be reduced significantly before long-range two-qubit gates with high fidelity can be reached [16,24]. Alternatively, symmetric exchange pulses can be implemented that perform fast, charge-insensitive gates [20,[25][26][27]. Even though the exchange interaction is intrinsically short-ranged, its range can be increased by means of a quantum mediator [28,29]. In particular, using a large multielectron quantum dot as an exchange mediator has the potential to do both: provide fast spin interaction [30,31] and alleviate spatial control line crowding. To avoid entanglement with internal degrees of freedom of the mediator, recent theory [30,31] motivates the use of a multielectron quantum dot with a spinless ground state and a level spacing sufficiently large to suppress unwanted excitations by gate voltage pulses.In this Letter, we investigate a GaAs multielectron quantum dot and show that its spin properties make it suitable for use as a coherent spin mediator. The experiment involves a chain of three quantum dots that can be detuned relative to each other using top-gate voltage pulses. The central one-electron dot serves as a probe: its spin can be tunnel coupled either to the left oneelectron dot (serving as a refe...