Tungstate and vanadate-doped polypyrrole/aluminum flake composite coatings for the corrosion protection of aluminum 2024-T3

Jadhav, Niteen; Jensen, Mark B.; Gelling, Victoria J.

doi:10.1007/s11998-014-9633-4

Cited by 21 publications

(5 citation statements)

References 86 publications

(97 reference statements)

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“…Bands at 801 cm −1 are due to the stretching vibration of V=O in the remaining V2O5 in the composite product. The peak of 560 cm −1 is due to the vanadate ion bond in the composites [27]. The SEM and EDX experiments confirmed that the synthesized product is a composite containing PPy and V2O5.…”

Section: Ftir Spectroscopic Analysismentioning

confidence: 61%

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Synthesis of Polypyrrole/V2O5 Composite Film on the Surface of Magnesium Using a Mild Vapor Phase Polymerization (VPP) Method for Corrosion Resistance

Sun

et al. 2020

Coatings

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The vapor phase polymerization (VPP) method is a conventional strategy for synthesizing conducting polymers (CPs) on the surfaces of various materials. However, the current VPP method performed on a metal surface usually requires harsh reaction conditions, such as high temperature and low vacuum. In this paper, a polypyrrole (PPy) and vanadium pentoxide (V2O5) composite film was synthesized on the surface of Mg using a mild VPP method. Here, V2O5 was used as an oxidant, and it was found that the oxidation of pyrrole (Py) vapor on the surface of V2O5, which had been previously coated on the surface of Mg, could be performed at room temperature under normal atmospheric pressure. The formation of the PPy/V2O5 composite was verified by Fourier transform infrared spectroscopy (FTIR) and energy dispersive X-ray (EDX) spectroscopy. A thermogravimetric analyzer (TGA) was used to study the thermal stability of the composite. Subsequent corrosion tests showed that the PPy/V2O5 composite film could slow down the corrosion of Mg in 3.5 wt% NaCl. It is expected that the mild VPP method may find great potential in the fields of synthesis of CPs and the corrosion protection of reactive metals.

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Section: Ftir Spectroscopic Analysismentioning

confidence: 61%

“…Jadhav [27] reported a PPy coating doped with vanadate and tungstate. With the degradation of PPy in the composite coating, the doped anions were released along with it, becoming a corrosion inhibitor in the system and slowing the corrosion of the aluminum substrate.…”

Section: Conductivitymentioning

confidence: 99%

Synthesis of Polypyrrole/V2O5 Composite Film on the Surface of Magnesium Using a Mild Vapor Phase Polymerization (VPP) Method for Corrosion Resistance

Sun

et al. 2020

Coatings

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“…Tungstate has a structure almost similar to molybdenum, but like molybdate cannot withstand electrochemical corrosion. According to [ 35 ], the presence of tungstate as impurities in poly(pyrrole) prevents the polymer defect and, to some extent, increases the corrosion resistance. However, after adding samarium tungstate nanoparticles to the pyrrole solution during electro-polymerization, the results were not as favorable as for SmM NPs@PP/GCE.…”

Section: Resultsmentioning

confidence: 99%

A Novel Electrochemical Aptasensor Based on a New Platform of Samarium Molybdate Flower-like Nanoparticles@Poly(pyrrole) for Non-Invasive Determination of Saliva CORTISOL

2022

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Cortisol, a famous stress biomarker, can be considered a potential predictor of cardiac diseases in humans. The presence of cortisol in saliva has encouraged researchers to design point-of-care devices for cortisol concentration in biological fluids. Here, human salivary cortisol was analyzed through a new non-invasive voltammetric aptasensor. Although cortisol is an electroactive compound, generally, the reduction in the current peak has been considered; however, this does not show a strong signal on a bare electrode surface, especially at low concentration levels. Hence, in this study, cortisol concentration was measured electrochemically and indirectly by monitoring the difference between electrochemical probe signals in the presence and absence of cortisol. A new polymeric nanocomposite of samarium molybdate flower-like nanoparticles decorated in poly(pyrrole) was electro-synthesized on the surface of a glassy carbon electrode. Then, reduced graphene oxide was cast on the surface. Finally, the cortisol aptamer was immobilized covalently on the reduced graphene oxide. This platform was used to increase the oxidation current peak of the ferricyanide solution as a probe as well as its electrocatalyst. The novel designed polymeric has the potential ability for effective immobilization of aptamers on the electrode surface without decreasing their biological activities. Additionally, it can enhance the probe electrochemical signal. The differential pulse voltammetric method (DPV) was applied as the detection technique. By optimizing the effective parameters, a determination range of 5.0 × 10−14–1.5 × 10−11 mol/L and a limit of detection of 4.5 × 10−14 mol/L were obtained. Selectivity of the proposed aptasensor relative to β-estradiol, progesterone and also prednisolone was studied as well. Finally, cortisol in a healthy human saliva sample was successfully analyzed by the proposed biosensors.

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“…The surfactant and oxidizing agent increased the conductivity and yield of polypyrrole [ 41 ]. Polypyrrole doped with tungstate or vanadate was synthesized by the chemical polymerization method and characterized by various techniques [ 42 ].…”

Section: Synthesis Of Conducting Polymersmentioning

confidence: 99%

“…Fillers also play a pivotal role towards modification in the semiconducting and electrochemical performance of CPs. Since past decades, a wide range of chalcogenides derived from transition metals has been employed as fillers for modification in semiconducting [ 2 ] and electrochemical performance of CPs [ 3 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 , 38 , 39 , 40 , 41 , 42 , 43 , 44 , 45 , 46 , 47 , 48 , 49 ], as illustrated in Table 1 . The product derived through the blending of such fillers with CPs is defined as PNCs.…”

Section: Introductionmentioning

confidence: 99%

Recent Trends and Developments in Conducting Polymer Nanocomposites for Multifunctional Applications

et al. 2021

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Electrically-conducting polymers (CPs) were first developed as a revolutionary class of organic compounds that possess optical and electrical properties comparable to that of metals as well as inorganic semiconductors and display the commendable properties correlated with traditional polymers, like the ease of manufacture along with resilience in processing. Polymer nanocomposites are designed and manufactured to ensure excellent promising properties for anti-static (electrically conducting), anti-corrosion, actuators, sensors, shape memory alloys, biomedical, flexible electronics, solar cells, fuel cells, supercapacitors, LEDs, and adhesive applications with desired-appealing and cost-effective, functional surface coatings. The distinctive properties of nanocomposite materials involve significantly improved mechanical characteristics, barrier-properties, weight-reduction, and increased, long-lasting performance in terms of heat, wear, and scratch-resistant. Constraint in availability of power due to continuous depletion in the reservoirs of fossil fuels has affected the performance and functioning of electronic and energy storage appliances. For such reasons, efforts to modify the performance of such appliances are under way through blending design engineering with organic electronics. Unlike conventional inorganic semiconductors, organic electronic materials are developed from conducting polymers (CPs), dyes and charge transfer complexes. However, the conductive polymers are perhaps more bio-compatible rather than conventional metals or semi-conductive materials. Such characteristics make it more fascinating for bio-engineering investigators to conduct research on polymers possessing antistatic properties for various applications. An extensive overview of different techniques of synthesis and the applications of polymer bio-nanocomposites in various fields of sensors, actuators, shape memory polymers, flexible electronics, optical limiting, electrical properties (batteries, solar cells, fuel cells, supercapacitors, LEDs), corrosion-protection and biomedical application are well-summarized from the findings all across the world in more than 150 references, exclusively from the past four years. This paper also presents recent advancements in composites of rare-earth oxides based on conducting polymer composites. Across a variety of biological and medical applications, the fact that numerous tissues were receptive to electric fields and stimuli made CPs more enticing.

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Tungstate and vanadate-doped polypyrrole/aluminum flake composite coatings for the corrosion protection of aluminum 2024-T3

Cited by 21 publications

References 86 publications

Synthesis of Polypyrrole/V2O5 Composite Film on the Surface of Magnesium Using a Mild Vapor Phase Polymerization (VPP) Method for Corrosion Resistance

Synthesis of Polypyrrole/V2O5 Composite Film on the Surface of Magnesium Using a Mild Vapor Phase Polymerization (VPP) Method for Corrosion Resistance

A Novel Electrochemical Aptasensor Based on a New Platform of Samarium Molybdate Flower-like Nanoparticles@Poly(pyrrole) for Non-Invasive Determination of Saliva CORTISOL

Recent Trends and Developments in Conducting Polymer Nanocomposites for Multifunctional Applications

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