Tungsten and molybdenum based polyoxometalates for photo and electrocatalytic carbon dioxide conversion – A critical review

Bhatt, Shivangini; Saha, Sumit

doi:10.1016/j.progsolidstchem.2023.100430

Cited by 3 publications

(3 citation statements)

References 148 publications

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“…Therefore, designing more effective POM‐based electrocatalysts for CO 2 RR with multicarbon products still needs further exploration. [ 122,123 ]…”

Section: Electrochemical Catalytic Merits Of Pom Molecules and Poms‐b...mentioning

confidence: 99%

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

Ma,

Yan,

et al. 2024

Advanced Materials

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Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical‐chemical properties, have made essential contributions to creating efficient and robust electrocatalysts in renewable energy systems. Due to the fundamental advantages of POMs, such as the diversity of molecular structures and large numbers of redox active sites, numerous efforts have been devoted to extending their application areas. Up to now, various strategies of assembling POM molecules into superstructures, supporting POMs on heterogeneous substrates, and POMs‐derived metal compounds have been developed for synthesizing electrocatalysts. From a multidisciplinary perspective, we systematically summarize the latest advances in creating POM‐structured materials with a unique focus on their molecular fundamentals, electrocatalytic roles, and the recent breakthroughs of POMs and POM‐derived electrocatalysts. Notably, we focus on exposing the current states, essences, and mechanisms of how POM‐structured materials influence their electrocatalytic activities and disclose the critical requirements for future developments. The future challenges, objectives, comparisons, and perspectives for creating POM‐structured materials have also been systematically discussed. We anticipate that this review will offer a substantial impact on stimulating interdisciplinary efforts for the prosperities and widespread utilizations of POM‐structured materials in electrocatalysis.This article is protected by copyright. All rights reserved

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“…Therefore, designing more effective POM‐based electrocatalysts for CO 2 RR with multicarbon products still needs further exploration. [ 122,123 ]…”

Section: Electrochemical Catalytic Merits Of Pom Molecules and Poms‐b...mentioning

confidence: 99%

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

Ma,

Yan,

et al. 2024

Advanced Materials

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“…Furthermore, their multi-metallic structure and highly dispersed ion coordination enable them to offer high activity and selectivity, resulting in an excellent performance in electrocatalytic reactions. 24 (III) POMs exhibit good stability in electrocatalytic reactions. Their multi-metallic structure and discrete ion coordination enable them to resist corrosion and structural degradation in oxidative, reductive, acidic, and alkaline environments, thus prolonging the service life of materials.…”

Section: Introductionmentioning

confidence: 99%

“…11,23 Moreover, POMs exhibit significant promise in reducing CO 2 emissions, given that they can convert greenhouse gases into valuable fuels and chemicals. 24…”

Section: Introductionmentioning

confidence: 99%

Recent research progress on polyoxometalate-based electrocatalysts in energy generation

Li,

Liu,

Ying

et al. 2024

J. Mater. Chem. A

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CeO2-based functional materials: Advancing photo and electro-driven catalysis for environmental remediation and energy conversion

Zhang,

Zhou,

Sun

et al. 2025

Coordination Chemistry Reviews

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Tungsten and molybdenum based polyoxometalates for photo and electrocatalytic carbon dioxide conversion – A critical review

Cited by 3 publications

References 148 publications

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

Recent research progress on polyoxometalate-based electrocatalysts in energy generation

CeO2-based functional materials: Advancing photo and electro-driven catalysis for environmental remediation and energy conversion

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