Tuning catalytic selectivity of liquid-phase hydrogenation of furfural via synergistic effects of supported bimetallic catalysts

Chen, Bingfeng; Li, Fengbo; Huang, Zhijun; Yuan, Guoqing

doi:10.1016/j.apcata.2015.05.006

Cited by 121 publications

(85 citation statements)

References 39 publications

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“…Ethanol has been proved to be favorable for high selectivity of obtaining THFA, though typical byproducts of 2-furaldehyde diethyl acetal (FDA) were formed in furfural hydrogenation process (see in Fig. S1) [18]. As far as we know, it has not been reported that the liquid-phase of direct hydrogenation of FFR to THFA using monometallic Ni supported on carbon nanotubes (CNTs) and ethanol as a solvent can be effective.…”

Section: Introductionmentioning

confidence: 98%

“…However, higher hydrogen pressure (80 bar) and lower reaction temperature (2 C) were needed to suppress the side reactions. Recently, Chen et al [18] investigated the hydrogenation of FFR to THFA over TiO 2 eZrO 2 -supported NiePd alloy catalyst. The catalyst with NiePd mole ratio of 5:1 (Ni: 5 wt%) gave the best performance.…”

Section: Introductionmentioning

confidence: 99%

“…Up to now, liquid-phase hydrogenation of FFR and FFA to THFA has been reported using both noble and non-noble metals catalysts. Conventional production of THFA is based on a two-step strategy: hydrogenation of FFR over CueCr catalyst and further hydrogenation of FFA to THFA over supported noble catalysts [18]. Most of the reports focus on liquidphase hydrogenation of FFA to THFA using supported Pt [19], Ru [20] and Ni [21] catalysts.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over Ni/CNTs and bimetallic Cu Ni/CNTs catalysts

Liu

Chen

2016

International Journal of Hydrogen Energy

151

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Section: Introductionmentioning

confidence: 98%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over Ni/CNTs and bimetallic Cu Ni/CNTs catalysts

Liu

Chen

2016

International Journal of Hydrogen Energy

151

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“…The reasons may include the adsorption of the oxygen atom of C O bond on the secondary metal atom and the induction of hydride-like nature on the active hydrogen species by the ligand effect. There are a number of reports on selective hydrogenation of furfural and HMF to FOL and BHF, respectively, using bimetallic catalysts such as M _ Re 46) 48) , M _ W 49) , M _ Fe 50),51) and M _ Sn 52) 54) (M noble metal, Cu or Ni). On the other hand, we have recently reported several bimetallic and trimetallic catalysts with good performance in total hydrogenation.…”

Section: Alloy Catalystsmentioning

confidence: 99%

Supported Metal Catalysts for Total Hydrogenation of Furfural and 5-Hydroxymethylfurfural

Nakagawa

Tamura

Tomishige

2017

J. Jpn. Petrol. Inst.

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Total hydrogenation of furfural and 5-hydroxymethylfurfural (HMF), both of which are important platform chemicals from biomass, produces tetrahydrofurfuryl alcohol (THFA) and 2,5-bis(hydroxymethyl)tetrahydrofuran (BHTHF), respectively, and these products can be used as solvent or raw material of resin. Ni catalysts can give good yields in these reactions; however the low activity and stability are problems. Supported monometallic Pd and Ru catalysts have been reported to be also active in hydrogenation, although the selectivity for total hydrogenation tends to be lower. Other monometallic catalysts such as Cu and Pt generally have low activity in furan ring hydrogenation of furfuryl alcohol (FOL) and 2,5-bis(hydroxymethyl)furan intermediates. We explored various multicomponent catalysts and found that Ni _ Pd/SiO2, Pd _ Ir/SiO2 and Rh _ Ir _ ReOx/SiO2 give good yield of THFA or BHTHF with much higher activity than the mixture of each component supported on SiO2.

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“…It could be seen that most of the Ni is the nickel (II) species, and the fractions of the nickel (II) species in all 0.2%Pd-x%Ni/SBA-15 catalysts were approximately 90%, and only a small fraction of Ni was nickel (0) for all samples regardless of the Ni loading amount. The presence of nickel oxide also indicated that there was an electron transfer between Pd and Ni; at the same time, the sample exposed to air would also lead to the formation of nickel oxide [47][48][49][50].…”

Section: Hydrogenation Of Cal To Hald Over Pd-ni/sba-15mentioning

confidence: 99%

Improvement Effect of Ni to Pd-Ni/SBA-15 Catalyst for Selective Hydrogenation of Cinnamaldehyde to Hydrocinnamaldehyde

et al. 2018

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Abstract:A series of Pd-Ni bimetallic catalysts supported on SBA-15 (0.2%Pd-x%Ni/SBA-15, x = 0.4, 0.7, and 1.2) were prepared through the impregnation method combined with the NaBH 4 reduction method. X-ray diffraction (XRD), N 2 adsorption-desorption, X-ray photoemission spectroscopy (XPS) and transmission electron microscope (TEM) were used to characterize the prepared catalysts. All the synthesized catalysts were evaluated for the liquid-phase hydrogenation of cinnamaldehyde (CAL). The addition of Ni obviously enhanced the CAL conversion and selectivity of C=C hydrogenation to hydrocinnamaldehyde (HALD) over the 0.2%Pd-x%Ni/SBA-15 catalysts. Meanwhile, 0.2%Pd-1.2%Ni/SBA-15 showed the best performance with 96.3% conversion and 87.8% selectivity toward HALD. This improvement was attributed to the synergistic effect between the Pd and Ni nanoparticles, enhancing the dispersion of Pd metal particles and increasing the content of surface Pd 0 species. In addition, the influences of a few reaction factors including H 2 pressure, reaction temperature, and reaction time were studied over 0.2%Pd-1.2%Ni/SBA-15.

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Tuning catalytic selectivity of liquid-phase hydrogenation of furfural via synergistic effects of supported bimetallic catalysts

Cited by 121 publications

References 39 publications

Selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over Ni/CNTs and bimetallic Cu Ni/CNTs catalysts

Selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over Ni/CNTs and bimetallic Cu Ni/CNTs catalysts

Supported Metal Catalysts for Total Hydrogenation of Furfural and 5-Hydroxymethylfurfural

Improvement Effect of Ni to Pd-Ni/SBA-15 Catalyst for Selective Hydrogenation of Cinnamaldehyde to Hydrocinnamaldehyde

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