Turning a yield-stress calcite suspension into a shear-thickening one by tuning inter-particle friction

Abstract

We show that a suspension of non-Brownian calcite particles in glycerol-water mixtures can be tuned continuously from being a yield-stress suspension to a shear-thickening suspension—without a measurable yield stress—by the addition of various surfactants. We interpret our results within a recent theoretical framework that models the rheological effects of stress-dependent constraints on inter-particle motion. Bare calcite particle suspensions are found to have finite yield stresses. In these suspensions, frictional contacts that constrain inter-particle sliding form at an infinitesimal applied stress and remain thereafter, while adhesive bonds that constrain inter-particle rotation are broken as the applied stress increases. Adding surfactants reduces the yield stress of such suspensions. We show that, contrary to the case of surfactant added to colloidal suspensions, this effect in non-Brownian suspensions is attributable to the emergence of a finite onset stress for the formation of frictional contacts. Our data suggest that the magnitude of this onset stress is set by the strength of surfactant adsorption to the particle surfaces, which therefore constitutes a new design principle for using surfactants to tune the rheology of formulations consisting of suspensions of adhesive non-Brownian particles.

Particle sizing for flowing colloidal suspensions using flow-differential dynamic microscopy

“…46 This suite of analysis methods and experimental protocols can therefore illuminate the yielding process in materials that are not amenable to particle-level methods, such as suspensions with complex interactions. 47,48…”

The physics of dense suspensions

“…In the absence of shear, meanwhile, numerical evidence (47) suggests that attraction reduces φm in non-Brownian, frictionless systems. Recent experimental measurements support the fact that weak attraction can enhance particle contacts (111) and even stabilise them against rolling (62). The combination of attraction and restricted tangential motion, adhesion (or cohesion if the particles are identical), generates a yield stress at lower volume fractions still, details of which are heavily protocol dependent (112).…”

Characterising shear-induced dynamics in flowing complex fluids using differential dynamic microscopy

“…47 This suite of analysis methods and experimental protocols can therefore illuminate the yielding process in materials that are not amenable to particle-level methods, such as suspensions with complex interactions. 48,49…”