An ultraviolet-visible spectrum between 300 and 450 nm of a cometary meteoroid originated from 55P/Tempel-Tuttle was investigated. The spectroscopy was carried out an intensified high definition TV camera with a slit-less reflection grating during the 2001 Leonid meteor shower over Japan. A best fit calculation mixed with atoms and molecules confirmed the first discovery of N + 2 B 2 Σ + u → X 2 Σ + g bands in the UV meteor spectrum. N + 2 temperature was estimated to 10,000 K with a low number density of 1.55 × 10 5 cm −3. We also discuss the possibility that enhanced emissions Preprint submitted to Elsevier Science in a meteor and a train around 310 nm are caused by the band head of OH A 2 Σ + → X 2 Π. Since cometary dust may have contributed organics and water to the Earth from its early period until now, OH AX (0,0) must be investigated.