2020
DOI: 10.26434/chemrxiv.13031843
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Twistable Dipolar Aryl Rings as Electric Field Actuated Conformational Molecular Switches

Abstract: The ability to control the chemical conformation of a system via external stimuli is a promsing route for developing molecular switches. For eventual deployment as viable sub-nanoscale components that are compatible with current electronic device technology, conformational switching should controllable by a local electric field (i.e. E-field gateable) and accompanied by a rapid change in conduction. In organic chemical systems the degree of π-conjugation is linked to the degree of electronic delocalisation, an… Show more

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