“…The emergence of the topological states in the twisted vdW heterostructures of HTSC BSCCO layers with the d ‐wave superconducting order parameter was suggested. [
25–30 ] The twist angle close to 45° was found to result in a time‐reversal symmetry (TRS) broken chiral superconducting
phase, which was also reported at the intermediate twist angles and was attributed to the unconventional sign structure of the d ‐wave order parameter. [
26,31 ] Strong support for this theoretical proposal came from the experimental detection of some new interfacial superconductivity, [ 23 ] manifesting as a dominant second harmonic of the Josephson current close to 45° angle.…”