Two 2D cobalt(II) coordination frameworks with unusual binodal network topology: synthesis, structures, and catalytic properties

Cobalt(II) and Copper(II) Complexes Constructed from Bis(benzimidazole) and 2,6‐Pyridinedicarboxylate Co‐ligands: Synthesis, Crystal Structures, and Catalytic Properties

“…H 2 O 2 is proven to be effective and highly active oxidizing species, that is because the reduction‐oxidation cycle of Cu II ‐Cu I and Co II ‐Co III producing hydroxyl radicals, and then azo dye reacts with hydroxyl radicals resulting oxidation products, such as CO 2 , H 2 O or other less toxic molecules, which seems to be a feasible method of the Fenton‐like degradation of congo red azo dye. A possible degradation mechanism can be suggested as follows:23…”

Tungsten Carbide–Nitride on Graphene Nanoplatelets as a Durable Hydrogen Evolution Electrocatalyst

“…Catalysis Experiments: The catalytic experiments were performed in a typical process as follows:24 powdered complex 15 mg was dispersed in a mixture of 200 mL of congo red solution (10 mg/L –1 , pH = 6.0) and 2 mL of 30 % (w/w) H 2 O 2 under magnetic stirring at 40 °C. 3 mL of the suspension was taken at given time intervals and separated through centrifugation.…”

Structural modulation of Co(II) coordination polymers with flexible bis(benzimidazole) and different dicarboxylate ligands

“…However, 2 still maintains a high catalytic activity and about 89.3% of the methyl orange dye is oxidized in the end. The difference catalytic performances of the two complexes may be due to the distinct coordination environments around the metal centers [42]. In the control experiments, the dissociation of methyl orange was no more than 19.0% without any catalyst indicating that persulfate alone is unable to effectively degrade the methyl orange.…”