Two chromium(II) complexes with amidato-like ligands: a compound with the longest CrCr bond and a mononuclear compound with D2d symmetry

Copper(II) Prevents the Saccarine-Dialkylcyanamide Coupling by Forming Mononuclear (Saccharinate)(Dialkylcyanamide)copper(II) Complexes

“…[41]. The bond length and angles for the saccharinate ligand were similar to those reported for the [Cr2L2(μ-sac)4] complexes (L = THF, Py) [42,43]. In addition, 3•2THF represents a rare reported example of saccarinate-based lantern-like complexes with a core {M2(Sac)4}.…”

catena-Poly[[μ-ethylenediamine-κ2N:N′-bis[(ethylenediamine-κ2N,N′)silver(I)] bis[silver(I)-μ-barbiturato-κ2N:N′]] dihydrate]

“…Barbituric acids coordinate through one or both deprotonated N atoms and ketone O atoms. Most studies have concentrated on the ®rst-row transition metals (Caira et al, 1973;Nassimbeni & Rodgers, 1974;Cotton et al, 1991) and relatively few studies have concerned barbituric acid complexes of platinum-group metals (Sinn et al, 1978;Fawcett et al, 1996) or silver and gold (Bonati et al, 1986). We report here the crystal structure of a novel silver(I) complex with barbiturate and ethylenediamine ligands.…”

Synthesis and structure of novel benzisothiazole-tetrazolyl derivatives for potential application as nitrogen ligands

“…Frija co-exist simultaneously as ionic and coordinated species in the same structure. As a ligand, it can be engaged in N, O(C O) or O(SO 2 ) coordination, but can also act as a bidentate amidato-like bridging agent [21][22][23]. The saccharinate anion interacts with metal centres in various ways, generating relatively strong interactions in crystalline environments, mostly through hydrogen bonding.…”