Two complexes isolated from solutions under solvothermal conditions: [CuCl2(C5H14N2)2]·4 H2O with the copper complex enwrapped in a unique self-assembled water layer of fused H2O decamers and [Co(CO3)(C5H14N2)2]Cl·H2O with the cobalt complex fixed in an extended hydrogen bond network

Synthesis, and Electrochemical and Density Functional Studies of New Copper(II)‐ and Manganese(II) Oxicam Drugs. Redox Potentials and MOs Compatible with SOD‐like Activity and Unusual Six‐membered Rings of Water Molecules Bridging Complex Units

“…As regards the arrangement of six H 2 O molecules (two aqua and four water) that pair two Cu II (HTEN) 2 entities, it has to be noticed that such a connection between coordination molecules has been found and reported for the first time (at our knowledge). Sheets of six-and ten-member rings of water molecules that are sandwiched by coordination molecules have recently been found [25] but the metals are not covalently connected to the water rings.…”

Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(iii/ii/iii) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study

“…found in a number of crystal hosts, have been extensively investigated. [57][58][59][60][61][62][63] A useful approach to the stabilization of water molecule aggregations is their capture within transition metal complex lattices formed by crystallization from aqueous solution. 57,[64][65][66][67][68][69][70][71][72][73][74][75][76][77] To study the supramolecular architecture of transition metal complexes in its solid state structure is receiving immense attention now-a-days.…”