2024
DOI: 10.1002/chem.202401203
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Two‐Coordinate Dinuclear Donor‐Gold(I)‐Acceptor Complexes Exhibiting Multiple Excitation Wavelength Dependent Phosphorescence

Jinfan Xiong,
Jia‐Xi Song,
Xiaoyong Chang
et al.

Abstract: Two‐coordinate Au(I) complexes with a donor‐metal‐acceptor (D‐M‐A) structure have shown rich luminescent properties. However, charge‐neutral dinuclear donor‐metal‐acceptor type Au(I) complexes featuring aurophilic interactions have been seldom explored. Herein, we describe the structures and photoluminescence properties of two dinuclear Au(I) complexes, namely DiAu‐Ph and DiAu‐Me. Single crystal X‐ray structural analysis of DiAu‐Ph reveals a short intramolecular Au‐Au distance of 3.224 Å. In dilute solution an… Show more

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