We prove that for κ ∈ (0, 8), if (η1, η2) is a 2-SLEκ pair in a simply connected domain D with an analytic boundary point z0, then as r → 0 + , P[dist(z0, ηj) < r, j = 1, 2] converges to a positive number for some α > 0, which is called the two-curve Green's function. The exponent α equals 12 κ − 1 or 2( 12 κ − 1) depending on whether z0 is one of the endpoints of η1 or η2. We also find the convergence rate and the exact formula for the Green's function up to a multiplicative constant. To derive these results, we construct two-dimensional diffusion processes and use orthogonal polynomials to obtain their transition density.