Two-dimensional correlation NMR study of the structure of by-product in the reaction of 2-methylquinoline with 3,5-di-tert-butyl-1,2-benzoquinone

Бородкин, Г. С.; Колодина, А. А.; Gusakov, Е. А.; Borodkina, I. G.; Chepurnoi, P. B.; Зайченко, С. Б.; Sayapin, Yu. A.

doi:10.1134/s1070428016070149

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Reactions Of Ortho‐benzoquinones1

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2019

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“…The structure of the minor product obtained in the reaction of 3,5‐di‐ tert ‐butyl‐1,2‐benzoquinone with 2‐methylquinoline in presence of acid was established by NMR studies as 10‐ tert‐ butylindolo[1,2‐ a ]quinoline‐8,11‐dione(Scheme ) …”

Section: Reactions Of Ortho‐benzoquinonesmentioning

confidence: 99%

Recent Advances and Prospects in the Chemistry of o‐Benzoquinones

et al. 2019

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Ortho‐benzoquinones play a vital role as reactive intermediate having high electrophilic character. Sterically crowded 1,2‐benzoquinones and their derivatives exhibiting divergent functionality have marked attraction in organic synthesis. Their intermolecular Diels‐Alder reactions reflect wide versatile applications. They act as a powerful tool towards the synthesis of biologically active complex heterocyclic ligands. This review focuses on the various novel advancements in the synthesis, reactions and applications of 1,2‐benzoquinones that have been achieved recently.

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Section: Reactions Of Ortho‐benzoquinonesmentioning

confidence: 99%