Abstract:Electronic modification of O-terminated ZnO(0001 _ ) and Znterminated ZnO(0001) by ethanethiol (C 2 H 5 SH) adsorption was investigated by angle-resolved photoelectron spectroscopy (ARPES) and X-ray photoelectron spectroscopy (XPS). Ethanethiol dissociates on both surfaces at room temperature to form C 2 H 5 S and H. The saturation coverage of ethanethiol is nearly three times larger on ZnO(0001) than on ZnO(0001 _ ). This suggests that Zn atoms exposed to the surface should act as adsorption and dissociation … Show more
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