Two-dimensional Metal-organic Frameworks and Derivatives for Electrocatalysis

Wen, Jinguli; Li, Yuwen; Gao, Jinghui

doi:10.1007/s40242-020-0163-6

Cited by 28 publications

(6 citation statements)

References 171 publications

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“…The 3D MOFs are in general have low conductivity and mass permeability and hence they have limited use as electrocatalysts. On the contrary, the porous 2D MOFs are advantageous in electrochemical applications, especially as electrocatalysts with improved mass and electron transfer ability. − They also have highly accessible active sites for electrocatalysis as well as the ease of exfoliation into nanosheets in the modular synthesis using the bottom-up approach. ,− …”

Section: Properties and Applicationsmentioning

confidence: 99%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties and applications, including gas and guest sorption, storage and separation of gases and small molecules, catalysis, luminescence, sensing, magnetism, and energy storage and conversion. Among MOFs, two-dimensional (2D) compounds are also known as 2D CPs or 2D MOFs. Since the discovery of graphene in 2004, 2D materials have also been widely studied. Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements. This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.

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Section: Properties and Applicationsmentioning

confidence: 99%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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“…Among them, the solvothermal method is the most widely used. Due to the large specific surface area of 2D materials, it is necessary to limit the growth in one direction during the synthesis of nanosheets [ 53 ]. Jia et al prepared a 2D NiFe MOF by a solvothermal method [ 54 ].…”

Section: Two-dimensional Materials In Oil–water Separationmentioning

confidence: 99%

Preparation of 2D Materials and Their Application in Oil–Water Separation

et al. 2023

Biomimetics

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The problems of environmental pollution are increasingly severe. Among them, industrial wastewater is one of the primary sources of pollution, so it is essential to deal with wastewater, especially oil and water mixtures. At present, biomimetic materials with special wettability have been proven to be effective in oil-water separation. Compared with three-dimensional (3D) materials, two-dimensional (2D) materials show unique advantages in the preparation of special wettable materials due to their high specific surface area, high porosity, controlled structure, and rich functional group rich on the surface. In this review, we first introduce oil–water mixtures and the common oil–water separation mechanism. Then, the research progress of 2D materials in oil–water separation is presented, including but not limited to their structure, types, preparation principles, and methods. In addition, it is still impossible to prepare 2D materials with large sizes because they are powder-like, which greatly limits the application in oil–water separation. Therefore, we provide here a review of several ways to transform 2D materials into 3D materials. In the end, the challenges encountered by 2D materials in separating oil–water are also clarified to promote future applications.

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“…43 Therefore, MOF-derived carboncontaining materials are extensively used as electrocatalysts. [44][45][46] The porous multifunctional structure of MOFs can be tuned via heteroatom-doping of carbon electrocatalysts obtained through calcination, such as N-, Fe-, Co-, and Nidoping, whereas some studies have suggested the use of the as-prepared MOFs for CO 2 RR without further treatment. In addition to the above-mentioned valuable properties, the synthesis of MOF materials is cost-effective, and MOFs can be converted into single-atom catalysts, metal nanoparticle catalysts, metal oxides and carbon-based catalysts via single-step heat treatment.…”

Section: Introductionmentioning

confidence: 99%

Clarifying the local microenvironment of metal–organic frameworks and their derivatives for electrochemical CO₂ reduction: advances and perspectives

et al. 2023

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Two-dimensional Metal-organic Frameworks and Derivatives for Electrocatalysis

Cited by 28 publications

References 171 publications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Preparation of 2D Materials and Their Application in Oil–Water Separation

Clarifying the local microenvironment of metal–organic frameworks and their derivatives for electrochemical CO₂ reduction: advances and perspectives

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Two-dimensional Metal-organic Frameworks and Derivatives for Electrocatalysis

Cited by 28 publications

References 171 publications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Preparation of 2D Materials and Their Application in Oil–Water Separation

Clarifying the local microenvironment of metal–organic frameworks and their derivatives for electrochemical CO2 reduction: advances and perspectives

Contact Info

Product

Resources

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Clarifying the local microenvironment of metal–organic frameworks and their derivatives for electrochemical CO₂ reduction: advances and perspectives