Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure

Zaguzin, A. S.; Spiridonova, Dar’ya V.; Novikov, Alexander S.; Рахманова, М. И.; Жеребцов, Д. А.; Федин, В. П.; Adonin, Sergey A.

doi:10.1007/s11172-023-3722-4

Russ Chem Bull

2023

DOI: 10.1007/s11172-023-3722-4

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Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure

A. S. Zaguzin

Dar’ya V. Spiridonova

Alexander S. Novikov

et al.

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Cited by 3 publications

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Structures of hexamethyl-[1,1′-biphenyl]-4,4′-diammonium salts

Kanthapazham,

Osipov,

Zherebtsov

et al. 2024

Acta Crystallogr B Struct Sci Cryst Eng Mater

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The crystal structures of nine hexamethyl-[1,1′-biphenyl]-4,4′-diammonium (HMB) salts are described: the iodide (2), triiodide (3), succinate (4), fumarate (5), tetravanadate (6), hydroterephthalate (7) and perylenetetracarboxylate (8), as well as pentamethyl-[1,1′-biphenyl]-4,4′-diammonium iodide (1) and the metal–organic framework sodium diacetylenedisalicylate–HMB (9). HMB carbonate (10) has been synthesized as an important intermediate for a promising anti-metal–organic framework (`anti-MOF'). All the described compounds are characterized by high solubility in water. The results suggest that, during crystallization, crystallohydrates are formed from water. Compounds 6 and 9 are characterized by the presence of a rigid framework; compound 6 has an open framework structure filled with water molecules. Synchronous thermal analyses of compounds 2, 4, 6, 7, 8 and 10 allowed the identification of similarities in the mechanisms of thermolysis. At about 80–180°C, the loss of crystallization water molecules occurs. Between 180 and 250°C, a methyl group (methyl cation) is split off from the quaternary ammonium salt to form tetramethylbenzidinium. In the case of the iodides and salts of organic acids, the second thermolysis product is the methyl ester of this acid (methyliodide, dimethyl carbonate), which easily evaporates. In the range 240–355°C, tetramethylbenzidinium evaporates without decomposition.

show abstract

Structures of hexamethyl-[1,1′-biphenyl]-4,4′-diammonium salts

Kanthapazham,

Osipov,

Zherebtsov

et al. 2024

Acta Crystallogr B Struct Sci Cryst Eng Mater

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Synthesis of New Copper(II) and Iron(III) Malonates with Barium Cations

et al. 2023

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3D Metal-Organic Coordination Polymers of Zn(II) Based on 1,2-Bis(4-pyridyl)ethylene and Anions of Iodoterephthalic and Iodoisophthalic Acids

Zaguzin,

Bondarenko,

Korobeynikov

et al. 2024

Russ. J. Inorg. Chem.

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Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure

Cited by 3 publications

References 57 publications

Structures of hexamethyl-[1,1′-biphenyl]-4,4′-diammonium salts

Structures of hexamethyl-[1,1′-biphenyl]-4,4′-diammonium salts

Synthesis of New Copper(II) and Iron(III) Malonates with Barium Cations

3D Metal-Organic Coordination Polymers of Zn(II) Based on 1,2-Bis(4-pyridyl)ethylene and Anions of Iodoterephthalic and Iodoisophthalic Acids

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