Two kinds of 2,4-dichlorobenzoate-based lanthanide coordination polymers tuned by 4,4′-bipyridine: Syntheses, structures, photoluminescence, and magnetism

Zhang, Ju‐Wen; Wang, Cen-Ru; Liu, Wenhua; Xu, Shuang; Liu, Bin-Qiu

doi:10.1016/j.ica.2020.119648

Cited by 9 publications

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“…4,4′-Bipyridine is a type of ligand that is often used in the synthesis to obtain coordination polymers. Such complexes exhibit very unique properties like photoluminescence or photochromism [ 25 , 26 , 27 , 28 ], biological [ 29 , 30 ] and magnetic properties [ 26 , 31 ], or the ability to detect or absorb harmful substances [ 32 , 33 , 34 , 35 ]. In this paper, we present synthesis, thermal properties, and crystal structures of two 4,4′-bipyridine coordination polymers with lanthanum (III) and samarium (III) dibromoacetates.…”

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confidence: 99%

Crystal Structures, Hirshfeld Surfaces, and Thermal Study of Isostructural Polymeric Ladders of La(III) and Sm(III) Coordination Compounds with 4,4’-Bipyridine and Dibromoacetates

et al. 2020

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Two novel mixed ligand complexes with general formula [M2(4,4′-bpy)1.5(CBr2HCOO)6(H2O)2]n (where 4,4′-bpy = 4,4′-bipyridine) were synthesized. Thermal analysis was used to describe a solid intermediate and final products of thermolysis. A coupled TG-MS system was used to monitor principal volatile fragments evolved during pyrolysis. Crystal structures of the complexes were determined. Cationic dinuclear M2 (M(III) = La, Sm) coordination cores were obtained. Both crystal structures are isostructural. Single crystal X-ray diffraction analysis revealed that investigated structures of 1D coordination polymers assembled in ladder-like systems. The central atom replacement resulted in unit cell identity parameter П = 0.0091. Additionally, the isostructurality of the reported La(III) and Sm(III) complexes was revealed using Hirshfeld Surface analysis supported by Enrichment Ratio calculations.

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