Two new clusters with Mn^II-Mn^IV magnetic exchange from the use of polyalcohol ligands

Precise Steric Control over 2D versus 3D Self-Assembly of Antimony(III) Alkoxide Cages through Strong Secondary Bonding Interactions

“…Noting this, we have designed a rigid antimony alkoxide cage (Scheme ) that is anticipated to facilitate three SBIs at the antimony center with one opposite to each primary bond which can lead to the predictable self-assembly of 2D bilayers when they arrange in an antiparallel fashion. It is notable that this type of triol has been used to support many different metal clusters; − however, with phosphorus and arsenic, the anticipated caged structure is obtained …”