2015
DOI: 10.1007/s13738-015-0686-9
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Two new organotin(IV)-phosphoryl complexes: crystal structure and Hirshfeld surface analysis

Abstract: in the asymmetric unit of (II) receives a second interaction from chlorine atom that, however, has negligible contribution portion in the total interactions (evaluated by fingerprint plot) in the crystal. On the other hand, this chlorine affects the geometry at the Sn atom and causes the open C-Sn-C bond angle (of 140.18(24)°). For both structures, the contribution of H…H contacts to the total interaction is decisive, being 59.1 % for (I) and 73.9 % for (II); so that the one distinct spike observed in each of … Show more

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