Two Novel Crystal Structures of 2-Mercapto-1,3,4-thiadiazole Complexes with Mercury (II) Chloride

Supramolecular aggregation featuring Hg⋯S secondary-bonding interactions in crystals of mercury(ii) species augmented by computational chemistry calculations

“…The aggregation patterns in closely related 38 (ref. 103) and 39 (ref. 104), in which the only difference between the molecules is that the latter has a methyl substituent, are distinct.…”

1,3,4-Thiadiazole and Its Derivatives: An Overview on Crystal Structure and Tribology Activities

“…(5) Hu et al (2010) effectively synthesized two complex structures of 1,3,4-thiadiazole crystal with metal, with yields of 85% and 5%, respectively. X-ray Diffraction analysis of crystals ( 6) and ( 7) revealed that Hg(II) of ( 6) is four coordinated with two chloride anions and two exocyclic sulphur atoms of two adjacent MTDs, and Hg(II) of ( 7) is three coordinated with one chloride anion, one nitrogen atom, and one exocyclic sulphur atom of two adjacent MTDs.…”