Two photoluminescent metal–organic frameworks based on a BODIPY-derived bipyridine ligand

Zhou, Lian; Xue, Yun-Shan; Xu, Yan; Zhang, Jun; Du, Hong‐Bin

doi:10.1039/c3ce41002a

Cited by 41 publications

(23 citation statements)

References 35 publications

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“…111 Topological analysis has revealed that the resulted MOF has a 2-fold interpenetrating 3D framework with an 8-connecting body centred cubic net, built upon a paddlewheel cluster (Figure 20d). This structure helped in eliminating the large voids leaving cuboid free spaces with triangular opening, exhibiting permanent porosity and gas adsorption property.…”

Section: Coordination-driven Bodipy Self-assemblymentioning

confidence: 99%

Self-Assembly of Bodipy-Derived Extended π-Systems

Cherumukkil

Vedhanarayanan

Das

et al. 2017

Bulletin of the Chemical Society of Japan

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Self-assembly is a viable approach to create soft functional materials with architectural diversity and property variations. Among the large number of different chromophores used, borondipyrromethene (Bodipy) dyes find a unique space because of their promising photophysical properties such as high molar absorptivity, fluorescent quantum yield and excellent photostability along with the associated synthetic ease. Recently, research on Bodipy dyes has experienced a surge of activities in view of favorable self-assembling properties. In this review, recent developments in self-assembled Bodipy dyes and their significance in various applications are discussed.

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Section: Coordination-driven Bodipy Self-assemblymentioning

confidence: 99%

Self-Assembly of Bodipy-Derived Extended π-Systems

Cherumukkil

Vedhanarayanan

Das

et al. 2017

Bulletin of the Chemical Society of Japan

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“…Materials 2020, 13, 2699 25 of 67 {Zn3(btc)2} or {Cd(bdc)} layers into 3D structures (Figure 9) [160]. Both MOFs exhibited similar emission spectra upon excitation at 512 nm in the solid state and emitted strong green light centered at 540 nm, similar to ligand L 1 in solution (Table 4).…”

Section: Ligands With Bodipy-type Fluorophoresmentioning

confidence: 95%

“…The combination of these qualities makes BODIPY fluorophores promising for the construction of highly luminescent coordination polymers, some of which were reviewed in 2016 [159]. 4) as struts linking {Zn 3 (btc) 2 } or {Cd(bdc)} layers into 3D structures (Figure 9) [160]. Both MOFs exhibited similar emission spectra upon excitation at 512 nm in the solid state and emitted strong green light centered at 540 nm, similar to ligand L 1 in solution (Table 4).…”

Section: Ligands With Bodipy-type Fluorophoresmentioning

confidence: 99%

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

et al. 2020

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Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020.

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“…A number of porous coordination networks (i.e., metal-organic frameworks, MOFs) bearing dipyrrin complexes have been developed and investigated. The dipyrrin ligands or BODIPYs that are connected to other coordination units serve as a multitopic ligand to form various self-assembled 3D networks (Béziau et al, 2013c , 2015 ; Zhou et al, 2013 ; Li et al, 2015 ).…”

Section: Infinite and Periodic Supramolecular Architectures And Theirmentioning

confidence: 99%

Functional Supramolecular Architectures of Dipyrrin Complexes

Matsuoka

Nabeshima

2018

Front. Chem.

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Dynamic formation of self-assemblies from molecular components is a useful and efficient way to produce molecular and supramolecular architectures with sophisticated functions. The labile coordination bond and dynamic covalent bond as a reversible bond have often been used to create a well-organized supramolecular self-assembly. In order to realize sophisticated novel functions of the supramolecular self-assemblies, dipyrrin complexes have recently been employed as a functional unit and incorporated into the supramolecular architectures because of their outstanding properties and functions such as a high photostability and strong light absorption/emission. This review article summarizes recent development in functional supramolecular architectures of the dipyrrin complexes produced by coordination to a metal ion and dynamic covalent bond formation. We first describe the synthesis and unique functions of a series of discrete supramolecular architectures: helicates, macrocycles, and cages. The polymeric supramolecular self-assemblies with 1D, 2D, and 3D structures are then introduced as a functional infinite supramolecular architecture.

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Two photoluminescent metal–organic frameworks based on a BODIPY-derived bipyridine ligand

Cited by 41 publications

References 35 publications

Self-Assembly of Bodipy-Derived Extended π-Systems

Self-Assembly of Bodipy-Derived Extended π-Systems

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

Functional Supramolecular Architectures of Dipyrrin Complexes

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