In [VAV11], Várilly-Alvarado and the last author constructed an Enriques surface X over Q with anétale-Brauer obstruction to the Hasse principle and no algebraic Brauer-Manin obstruction. In this paper, we show that the nontrivial Brauer class of X Q does not descend to Q. Together with the results of [VAV11], this proves that the Brauer-Manin obstruction is insufficient to explain all failures of the Hasse principle on Enriques surfaces.The methods of this paper build on the ideas in [CV14a,CV14b,IOOV]: we study geometrically unramified Brauer classes on X via pullback of ramified Brauer classes on a rational surface. Notably, we develop techniques which work over fields which are not necessarily separably closed, in particular, over number fields.