2024
DOI: 10.1002/chem.202401033
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U(V) Stabilization via Aliovalent Incorporation of Ln(III) into Oxo‐salt Framework

Yi Yu,
Yucheng Hao,
Bin Xiao
et al.

Abstract: Pentavalent uranium compounds are key components of uranium‘s redox chemistry and play important roles in environmental transport. Despite this, well‐characterized U(V) compounds are scarce primarily because of their instability with respect to disproportionation to U(IV) and U(VI). In this work, we provide an alternate route to incorporation of U(V) into a crystalline lattice where different oxidation states of uranium can be stabilized through the incorporation of secondary cations with different sizes and c… Show more

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