Über den zustand gelöster verbindungen in wasserfreier essigsäure

Potentiometric Electrode Systems In Nonaqueous Titrimetry

“…The titration cell, which incorporates the recommended gold electrodes, is shown diagrammatically in figure 2. It appears that gold electrodes can be used to follow acetate-ion concentration in studies in glacial acetic acid (96). The ionic product for anhydrous acetic acid has been measured (97).…”

Anhydrous Acetic Acid as Nonaqueous Solvent

“…Sodium or ammonium acetates were used as electrolytes. They attribute this anomaly to the reaction Py + HOAc -> PyH + + OAc" (88) Ghronopotentiometric studies of thallium ion in glacial acetic acid was carried out by Bruckenstein et al 270 It was found that the thallium acetate-Tl-Hg couple was reversible and the formal potential vs. aqueous see was 0.347 ±0.005 V. In general, the data indicate formation of monopositive ions, which, in the case of Ga, In, and Al either disproportionate to give tripositive ions and the metal, 3In + ->In 3+ +2In (86) or are oxidized by the solvent, Al + + 2HOAc + AcO--> Al(OAc) 3 + H 2 (87) Kinetics of electrooxidation of pyridine in anhydrous acetic acid have been studied in the 70° to 300°G temperature range by Aboimov and Gorbachev.…”