Über die rolle der Sulfationen bei der anodischen Auflösung und bei der Passivierung von Nickel

The characteristics of the potentiodynamic potential/current profiles obtained with the Ni/0.5N H2SO4 interface. A contribution to the mechanism of the electrode process

“…This is actually the case concerning the participation of sulphate ions in the kinetics of the anodic dissolution and passivation of nickel in acid electrolytes. 67…”

Electrodissolution Kinetics of Nickel in Concentrated Acidic Chloride Solutions

“…There have been a number of studies indicating the direct participation of anions, particularly CI-, in the electrodissolution of iron (4)(5)(6)(14)(15)(16)(17)(18). Such anion effects on anodic nickel dissolution have also been reported (19)(20)(21)(22) but others, on the other hand, have observed no such effects (23,24).…”

Chemisorption model of electrochemical passivity of metals and thermodynamic calculation of the flade potential of metals Ni and Cr taking into account their surface Gibbs energy

“…It is worth noting that the curve exhibits two anodic peaks, which have been previously described by Sury [25], Kesten and Feller [26], and Marshakov et al [27]. It is believed that the first peak is attributed to the primary passivation of Ni [25].…”

“…(25) will be as follows: (26) Hence, using the equation to convert the energy of formation of surface oxide Me m O n to electrochemical energy, we obtain the formula for cal culating the Flade potential of pure metals in an aque ous solution:…”