Über die Struktur und Eigenschaften der Halbmetalle. VIII. Die katalytische Darstellung des schwarzen Phosphors

Krebs, H.; Weitz, H. M.; Worms, K. H.

doi:10.1002/zaac.19552800110

Cited by 112 publications

(57 citation statements)

References 17 publications

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“…[49] In this synthetic procedure,w hite phosphorus was treated with 30-40 at. [49] In this synthetic procedure,w hite phosphorus was treated with 30-40 at.…”

Section: Bulk Black Phosphorusmentioning

confidence: 99%

Black Phosphorus Rediscovered: From Bulk Material to Monolayers

2017

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Phosphorus is a nonmetal with several allotropes, from the highly reactive white phosphorus to the thermodynamically stable black phosphorus (BP) with a puckered orthorhombic layered structure. The bulk form of BP was first synthesized in 1914, but received little attention until it was rediscovered in 2014 as a member of the new wave of 2D layered nanomaterials. BP can be exfoliated to a single sheet that acts as a semiconductor with a tunable direct band gap, a high carrier mobility at room temperature, and an in-plane anisotropy. The development of BP applications is hampered by surface degradation, thus efforts to achieve effective BP passivation are ongoing, such as its integration in van der Waals heterostructures. BP has been tested as a novel nanomaterial in batteries, transistors, sensors, and photonics. This Review begins with the origin of the BP story, following the path from a bulk material to modern few/single layers. The physical and chemical properties are summarized, and the state-of-the-art of BP applications highlighted.

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“…[49] In this synthetic procedure,w hite phosphorus was treated with 30-40 at. [49] In this synthetic procedure,w hite phosphorus was treated with 30-40 at.…”

Section: Bulk Black Phosphorusmentioning

confidence: 99%

Black Phosphorus Rediscovered: From Bulk Material to Monolayers

2017

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“…[178][179][180] Due to the unique layered structure, excellent physical properties and unusual anisotropy of BP, it has great potential in field effect transistors, photodetectors, thermoelectric applications, and solar cells. [181][182][183][184] Because of its great application prospects, so far, a lot of ways have been figured out to prepare BP, such as the widely used high-pressure and high-temperature method, [69,[185][186][187] mercury method, [188] bismuth flux method, [189] high-energy mechanical milling and chemical vapor transport method. [190,191] All these methods have their own advantages and limits.…”

Section: Bp-based Anode Materials For Libs and Sibsmentioning

confidence: 99%

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

173

128

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High‐performance and lost‐cost lithium‐ion and sodium‐ion batteries are highly desirable for a wide range of applications including portable electronic devices, transportation (e.g., electric vehicles, hybrid vehicles, etc.), and renewable energy storage systems. Great research efforts have been devoted to developing alternative anode materials with superior electrochemical properties since the anode materials used are closely related to the capacity and safety characteristics of the batteries. With the theoretical capacity of 2596 mA h g−1, phosphorus is considered to be the highest capacity anode material for sodium‐ion batteries and one of the most attractive anode materials for lithium‐ion batteries. This work provides a comprehensive study on the most recent advancements in the rational design of phosphorus‐based anode materials for both lithium‐ion and sodium‐ion batteries. The currently available approaches to phosphorus‐based composites along with their merits and challenges are summarized and discussed. Furthermore, some present underpinning issues and future prospects for the further development of advanced phosphorus‐based materials for energy storage/conversion systems are discussed.

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“…However, this method requires expensive and sophisticated equipment, which limits the fundamental research, applications and commercial popularization of o-BP single crystal. Besides this conventional preparation technique, the controllable synthesis of o-BP single crystal also can be attained by other ways including recrystallization from mercury [41,42] or bismuth-flux method [42−44] and mineralizer-assisted chemical vapor transport (CVT) reaction method [45−48]. Among these, the mercury or bismuth-assisted method provides a viable path for preparing o-BP single crystals.…”

Section: Articlesmentioning

confidence: 99%

Two-step heating synthesis of sub-3 millimeter-sized orthorhombic black phosphorus single crystal by chemical vapor transport reaction method

et al. 2016

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(Ren TL)) spotlight due to its excellent room-temperature carrier mobility and layer-dependent direct band gap, which can be tuned from 0.3 to 2 eV as its thickness decreases from bulk to monolayer [5−8]. Therefore, o-BP is prized in bridging the gap between graphene and TMDCs. Accordingly, phosphorene, which is designated as a monolayer or a few layers of o-BP, has recently emerged as a new promising member of the 2D material family. Based on its intriguing properties, a plethora of exciting potential applications of monolayer or multilayer phosphorene have been reported, such as field-effect transistors (FETs) [5,9−13] [27,28]. Specifically, much interest has been focused on FETs based on multilayer phosphorene, stemming from its fascinating electrical properties. These FETs devices show the appreciable hole mobility (μ p ) in the order of 10 to 10 3 cm 2 V −1 s −1 and the on/off current switching ratio (I on /I off ) of 10 2 to 10 4 [5,9−13]. The theoretically predicted μ p for the monolayer or multilayer phosphorene at room temperature is infrequently high (10,000−26,000 cm 2 V −1 s −1 ) [9,11], and the I on /I off is remarkable large (exceeding 10 5 ) [5,9]. The implementation of monolayer or multilayer phosphorene can be attained by several classical methods including bottom-up processes, solution-based approaches [26,29−32], top-down methods [5,9−13]. Among these, although the bottom-up direct synthesis of large-area monolayer or multilayer phosphorene is the most promising way, by its reality, it has not yet been realized. The solution-based approaches have serious negative influences on both quality and purity of monolayer or multilayer phosphorene. The top-down methods are explored to achieve monolayer or multilayer phosphorene

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Über die Struktur und Eigenschaften der Halbmetalle. VIII. Die katalytische Darstellung des schwarzen Phosphors

Cited by 112 publications

References 17 publications

Black Phosphorus Rediscovered: From Bulk Material to Monolayers

Black Phosphorus Rediscovered: From Bulk Material to Monolayers

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Two-step heating synthesis of sub-3 millimeter-sized orthorhombic black phosphorus single crystal by chemical vapor transport reaction method

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