Über pflanzliche Fischgifte, V. Mitteil.: Die Konstitution des Imperatorins (aus Imperatoria Ostruthium)

Späth, Ernst; Holzen, Herbert

doi:10.1002/cber.19330660823

Cited by 48 publications

(4 citation statements)

References 14 publications

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“…13 C-NMR (CDCl 3 ) δ ppm: 161.4 (C-2), 158.7 (C-7), 153.0 (C-8a), 149.1 (C-5), 144.9 (C-2'), 140.1 (C-4"), 139.6 (C-4), 119.4 (C-3"), 116.7 (C-6), 112.6 (C-3), 107.6 (C-4a), 105.0 (C-3'), 94.3 (C-8), 69.8 (C-2"), 26.4 (C-5''), 18.1 (C-6''). The above data were consistent with the literature data [20,21].…”

Section: Methodssupporting

confidence: 93%

Cytotoxic Constituents from the Stems of Clausena lansium (Lour.) Skeels

Jiang

Wang

Fan³

et al. 2013

Molecules

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Six compounds were isolated from the stems of Clausena lansium (Lour.) Skeels by repeated sillica gel column chromatography. Their chemical structures were elucidated on the basic of physicochemical and spectroscopic data. Among them, 8-geranyloxypsolaren (3) and 2-methoxy-1-(3-methyl-buten-1-yl)-9H-carbazole-3-carbaldehyde (6) were isolated for the first time from this plant. These compounds were screened for cytotoxicity in human cervical cancer (Hela), leukemia (K562), lung cancer (A549), non-small lung carcinoma (H1299) and liver cancer . Within the series of cytotoxic tests, compounds 4-6 displayed potent cytotoxic activity against H1299 and SMMC-7721, with the IC 50 values of 6.19 to 26.84 μg/mL.

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Section: Methodssupporting

confidence: 93%

Cytotoxic Constituents from the Stems of Clausena lansium (Lour.) Skeels

Jiang

Wang

Fan³

et al. 2013

Molecules

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“…The resulting solution of phenyldichlorostibine was hydrolyzed by dilute aqueous ammonia or sodium hydroxide. 3 The precipitated stibosobenzene was washed with 10 to 12 liters of water, alcohol and ether, and dried in vacuo.…”

Section: Methodsmentioning

confidence: 99%

Disproportionation of Aromatic Stiboso Compounds. I. Mechanism

Hh¹,

Go²

1949

J. Am. Chem. Soc.

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Hexafluorobutadiene has been shown to be a highly reactive compound resembling in general butadiene rather than the relatively inert hexachlorobutadiene.The thermal reactions of hexafluorobutadiene were investigated over the temperature range 150 to 180°and hexafluorocyclobutene, dimers, which were formed in largest amount, and trimers isolated as the principal products.Hexafluorobutadiene dimer and trimer fractions were shown to be mixtures of isomers. On heating, the dimer was partially converted into a remarkable lower-boiling saturated and highly stable isomer for which a fused tricyclic structure was proposed. Hexafluorobutadiene trimer polymerized slowly on heating. Both dimer and trimer were partially depolymerized by passing through a hot tube.11 haca, X. Y.

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“…Of these, imperatorin, isoimperatorin, oxypeucedanin, and ostruthol have been completely investigated. Imperatorin and isoimperatorin are isomeric (233,239). Oxypeucedanin, present in the roots of Peucedanum officinale (Umbelliferae) and known for nearly a century, has been investigated only in recent years (236).…”

Section: Coohmentioning

confidence: 99%