Ultra-high Seebeck coefficient of a thermal sensor through entropic optimisation of ligand length of Fe(ii) spin-crossover (SCO) materials

Abstract

The molecular optimisation strategies exhibit ultrahigh Seebeck coefficient through a six-pronged approach to maximise entropy during the transition from low spin (LS) to high spin (HS).

High-Power-Density Thermoelectrochemical Cell Based on Ni/NiO Nanostructured Microsphere Electrodes with Alkaline Electrolyte

“…In this case, the change in potentials, as well as the regularity of the intensity of the interaction of nickel spheres on cold and hot electrodes, according to the equations presented above, has a more complex dependence on the concentration. This explains the absence of a direct dependence in the values of the Seebeck coefficient and, accordingly, in the values of the open-circuit voltage at various temperature gradients between the electrodes and at various electrolyte con- It is widely known that the Seebeck coefficient of the system has a pronounced entropic nature [17,44,45]. With an increase in the alkali concentration, the interaction of the oxide phase of the Ni/NiO spheres with OH − ions should also be enhanced.…”

“…It is widely known that the Seebeck coefficient of the system has a pronounced entropic nature [ 17 , 44 , 45 ]. With an increase in the alkali concentration, the interaction of the oxide phase of the Ni/NiO spheres with OH − ions should also be enhanced.…”