2022
DOI: 10.1039/d2mh00718e
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Ultra-stable self-standing Au nanowires/TiO2nanoporous membrane system for high-performance photoelectrochemical water splitting cells

Abstract: Here we introduce for the first time a synthesis method of a core–shell photoanode composed of nanostructured self-standing titania nanotubes filled with Au nanowires. Photoanode shows high photon to current efficiency of 35% and incredible stability.

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Cited by 18 publications
(14 citation statements)
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“…The two peaks, Ti 2p 3/2 and Ti 2p 1/2 , correspond to binding energies of 458.24 and 463.94 eV, respectively. The distance 5.7 eV between the two Ti 2p peaks indicates that all of the Ti in the PPM + TiO 2 NPs sample is in the valence state of Ti 4+ [ 28 ]. Two deconvoluted O 1s peaks are shown in Figure 6 c. The lower binding energy peak at 529.25 eV is assigned to Ti–O bonds in the O 2− chemical state of the TiO 2 lattice.…”
Section: Resultsmentioning
confidence: 99%
“…The two peaks, Ti 2p 3/2 and Ti 2p 1/2 , correspond to binding energies of 458.24 and 463.94 eV, respectively. The distance 5.7 eV between the two Ti 2p peaks indicates that all of the Ti in the PPM + TiO 2 NPs sample is in the valence state of Ti 4+ [ 28 ]. Two deconvoluted O 1s peaks are shown in Figure 6 c. The lower binding energy peak at 529.25 eV is assigned to Ti–O bonds in the O 2− chemical state of the TiO 2 lattice.…”
Section: Resultsmentioning
confidence: 99%
“…After the deposition of AuNPs on the TiO 2 surface, a second more negative flat band energy can be observed, and it is related to the formation of the Schottky barrier at the semiconductor-/metal interface. These observations are consistent with literature reports . Moreover, the donor densities were estimated for both photoelectrodes (Figure B), and an increase in the donor density from 1.2 × 10 –19 cm –3 for TiO 2 to 1.5 × 10 –19 cm –3 for TiO 2 /Au was observed (for details, see Table S2, Supporting Information).…”
Section: Resultsmentioning
confidence: 99%
“…These observations are consistent with literature reports. 63 Moreover, the donor densities were estimated for both photoelectrodes (Figure 8B), and an increase in the donor density from 1.2 × 10 −19 cm −3 for TiO 2 to 1.5 × 10 −19 cm −3 for TiO 2 /Au was observed (for details, see Table S2, Supporting Information).…”
mentioning
confidence: 93%
“…The anion free radical of cO 2− reacts with most organic compounds by oxidation to generate CO 2 and H 2 O, 36,37 while the hole oxidizes OH and H 2 O adsorbed on the surface of TiO 2 to cOH. 38,39 At the same time, cO 2− reacts with H 2 O oxidizing it to cOH. cOH has a strong oxidizing ability, which can attack organic compounds and extract H atoms to generate new free radicals, stimulate chain reactions and lead to the decomposition of organic matter.…”
Section: Visual Sensor Photocatalytic Decomposition Of Organic Mattermentioning
confidence: 99%