Researches based on conceptual plasmoelectric devices such as photodetectors, [3] photovoltaic devices, [4] and plasmonic tunneling junction memristors, [5] have been found to have some unusual electron transport properties [6,7] of the materials and devices. In such devices, plasmons and electromagnetic field enhancement can be driven either by optical illumination or electrically. The optically excited plasmons mode usually couples with the incident light to transfer the energy of localized surface plasmon resonance (LSPR) to carriers directly by plasmons decay nonradiatively; [8] while electrically driven plasmons, as recently been diversely demonstrated, require efficient nanoscale integration of electrical and optical circuits and optoelectronic conversion which influence carriers dynamics by exciting plasmonic fields based on special plasmonic nanomaterials. [9,10] Diodes with unidirectional rectifying behavior are important components of modern electronic devices such as integrated circuits, photodetectors, and luminescent devices, etc. Basically, rectification behavior occurs at asymmetric interfaces such as p-n junctions or metal/ semiconductor interfaces with Schottky barriers, [11,12] where diverse plasmonic metal nanostructure/semiconductor hybrid heterojunctions can be introduced to enhance the efficiency of electrons transport and photoexcitation through subwavelength optical manipulation. [13,14] Although the metal/semiconductor heterojunction-based devices with plasmonic subwavelength optoelectronic properties have been reported for energy conversion study, [15][16][17] no attempts were reported so far on manipulating plasmoelectronic property of plasmonic nanostructures at the metal/semiconductor interfaces for potential diode applications. Moreover, recently diodes based on 2D materials (graphene, MXene, and transition metal dichalcogenides, etc.) have aroused increasing interest due to their giant potentials to surpass Moore's law. [18,19] Therefore, 2D plasmonic nano materials with symmetric and integrated subwavelength structures aroused our attention as they showed higher light-harvesting efficiency and electromagnetic field enhancements (achieved more easily over large areas in 2D plasmonic nanostructures) than their 1D counterparts. [20][21][22] Recently, we and others have revealed some interesting phenomenon and properties of electrons transport based on 2D plasmonic nano membrane, such as plasmon-enabled long-range electron tunneling Electronic devices with rectifying effect are typical building blocks for integrated circuits and useful for photodetectors. Herein, a new type of diode based on plasmonic tunnel hetero-nanostructure is reported. By constructing a planar plasmoelectric junction between p-Si and Au pad electrode with a few-layer-stacked 2D plasmonic AuNP-nanomembrane as a medium layer, rectifying behavior of the device is achieved, though the direct contact between bulk Au and semiconductor usually tends to form ohmic contact. The electrically driven plasmons enable the 2D A...