Terahertz (THz) pulses with energies up to 100 μJ and corresponding electric fields up to 1 MV=cm were generated by coherent transition radiation from 500 MeV electron bunches at the free-electron laser Freie-Elektronen-Laser in Hamburg (FLASH). The pulses were characterized in the time domain by electro-optical sampling by a synchronized femtosecond laser with jitter of less than 100 fs. High THz field strengths and quality of synchronization with an optical laser will enable observation of nonlinear THz phenomena. © 2011 Optical Society of America OCIS codes: 120.6200, 140.2600, 320.7110.Intense single-cycle terahertz (THz) pulses are increasingly being used to observe extreme nonlinear optical phenomena at high field strengths [1][2][3]. These pulses can be obtained on the tabletop by optical rectification of femtosecond laser pulses and can reach pulse energies on the level of tens of microjoules [4]. Even higher pulse energies and fields can potentially be reached by accelerator-based sources [5,6]. Coherent transition radiation (CTR) is emitted when an electron bunch crosses the boundary between two media [7,8]. The energy of the pulses scales with the average line charge density ("peak current") of the bunch squared and their frequency content covers the THz up to the IR region of the electromagnetic spectrum, depending on the electron bunch duration. Since the driving linear accelerators for highgain free-electron lasers (FELs) are built to boost the peak current to several kiloampere, they are well suited to drive powerful CTR sources. A number of high-gain xray FEL facilities are now developing a complementary THz research program with short broadband THz pulses. At the soft x-ray FEL Freie-Elektronen-Laser in Hamburg (FLASH) [9], transition radiation is generated from collision of electron bunches with energies up to 1:2 GeV with a metal screen and then guided through an evacuated beam line [10] with 20 m length into a user accessible lab. While the main purpose of this beam line is highresolution diagnostics of the longitudinal electron bunch characteristics [11], it can also serve as a powerful and broadband source for experiments with subpicosecond single-cycle pulses. The pulses obtained have energies exceeding 100 μJ and span a frequency band of 200 GHz to 100 THz. Here we determine the temporal structure and the electric field of the THz pulse below 10 THz directly in the time domain using electro-optic sampling with a femtosecond laser synchronized to the electron bunches. The availability of optical probe lasers synchronized to this intense THz source enables THz pump optical probe measurements.The CTR source at FLASH is located in a straight section between the superconducting linear accelerator and the undulator. The last electron bunch within a sequence of up to 800 bunches with a spacing of 1 μs can be deflected onto an off-axis CTR target by a fast kicker magnet without interfering with routine FEL user operation at the x-ray undulator downstream. The CTR radiation is produced on a metal ...