Dynamical quantum phase transitions (DQPTs) extend the concept of phase transitions and thus universality to the non-equilibrium regime. In this letter, we investigate DQPTs in a string of ions simulating interacting transverse-field Ising models. We observe non-equilibrium dynamics induced by a quantum quench and show for strings of up to 10 ions the direct detection of DQPTs by measuring a quantity that becomes non-analytic in time in the thermodynamic limit. Moreover, we provide a link between DQPTs and the dynamics of other relevant quantities such as the magnetization, and we establish a connection between DQPTs and entanglement production.Today, the equilibrium properties of quantum matter are theoretically described with remarkable success. Yet, in recent years pioneering experiments have created novel quantum states beyond this equilibrium paradigm [1,2]. Thanks to this progress, it is now possible to experimentally study exotic phenomena such as many-body localization [3,4], prethermalization [5, 6], particle-antiparticle production in the lattice Schwinger model [7], and light-induced superconductivity [8]. Understanding general properties of such nonequilibrium quantum states provides a significant challenge, calling for new concepts that extend important principles such as universality to the non-equilibrium realm. A general approach towards this major goal is the theory of dynamical quantum phase transitions (DQPTs) [9], which extends the concept of phase transitions and thus universality to the nonequilibrium regime. In this letter, we directly observe the defining real-time non-analyticities at DQPTs in a trappedion quantum simulator for interacting transverse-field Ising models. Moreover, we provide a link between DQPTs and the dynamics of other relevant quantities such as the magnetization, and we establish a connection between DQPTs and entanglement production. Our work advances towards experimentally characterizing nonequilibrium quantum states and their dynamics, by offering general experimental tools that can be applied also to other inherently dynamical phenomena.Statistical mechanics and thermodynamics provide us with an excellent understanding of equilibrium quantum manybody systems. A key concept in this framework is the canonical partition function Z(T ) = Tr(e −H/k B T ), with T the temperature, k B the Boltzmann constant, and H the system Hamiltonian. The partition function encodes thermodynamics via the free-energy density f = −(k B T/N) log [Z(T )], where N de- * Present address:ARC Centre of Excellence for Engineered Quantum Systems, School of Physics, University of Sydney, NSW, 2006, Australia notes the number of degrees of freedom. A phase transition, i.e., a sudden change of macroscopic behaviour, is associated with a non-analytical behaviour of f as a function of temperature or another control parameter g such as an external magnetic field. Quantum phase transitions (QPTs) [10] occur when T is kept at absolute zero, where the system's groundstate properties undergo a non-analyt...