large nonlinear index of refraction (n 2 -10-4 m 2 /w with fast response times (r < 16 psec) required for high speed optical signal processing.Of the number of processing techniques which exist for producing optical waveguides from glass based materials, ion-exchange is one of the most flexible and l easiest to implement.We have now established a very successful potassium (K+)/sodium (Na + ) ion-exchange technique' for producing low-loss (few dB/cm) eplanar waveguides. This process is also amenable to producing channel waveguide structures and devices which we are also undertaking. Dr Lee-Giles.
202-767-4933Electronic Material -2-We are currently assessing these semiconductor-doped glass waveguides for application to this waveguide DFWM program. One area of concern is the effect of the ion-exchange process on the nonlinear response of the material since we are not achieving the expected rey.onse from waveguide samples which, previous to processing, were showing large DFWM signals in bulk form. Whilst working on this problem we are also developing waveguides utilizing the semiconductor-doped glass as the nonlinear substrate material. These are produced by RF sputtering of a higher index glass film onto the nonlinear substrate to produce the waveguide. Very lowloss waveguides have been produced by sputtering of PSK-2 glass onto the prepolished color-filters and experiments are in progress to attempt waveguide DFWM in this similar geometry to the CS 2 case but with a higher nonlinearity medium surrounding the guiding layer.The other major avenue of research pertaining to this program is the use of nonlinear organic materials for waveguide optical signal processing applications. A number of reports of large and fast responding nonlinearities have been made recently and we are currently testing materials of this form from the Celanese Corporation. We spin thin films of company propriotory organic materials onto fused silica and glass substrates and have achieved relatively low-loss guiding (-ldB/cm). The coupling process is achieved by using physical relief gratings on the substrate since prism coupling can seriously damage such mechanically soft films.Other sources of nonlinear organic materials are also being pursued (SUNY Buffalo; JPL) and the possibility of producing nonlinear organic films by deposition in our Langmuir-Blodgett tank is still in our plans. We have succeeded'in producing Degenerate four-wave mixing in a thin-film waveguide is demonstrated for the first time. A reflectivity of 10-at a power density of 5 MW/cm 2 was obtained for liquid CS 2 placed on top of a glass waveguide.Degenerate four-wave mixing (DFWM) is a phenoum over the part of the waveguide where the beams intersect. menon of considerable interest because of its applications toThe liquid was held in place by a hollowed out glass cell optical signal processing.' Nonlinear signal delay lines,' whose bottom surface was well polished and optically contime reversal of optical pulses, 2 optical computing, 3 bistabitacted to the thin-film surfa...